兰州城市学院 化学与环境工程学院,甘肃,兰州,730070
纸质出版:2018
移动端阅览
郑艳萍, 刘芳, 孙看军, 等. 麦麸纤维素与腐植酸复合保水剂的制备及性能[J]. 水土保持通报, 2018,38(2):253-257.
ZHENG Yanping, LIU Fang, SUN Kanjun, et al. Synthesis and Property of Superabsorbent Compound of Cellulose Extracted from Wheat Bran with Humic Acid[J]. Bulletin of Soiland Water Conservation, 2018, 38(2): 253-257.
郑艳萍, 刘芳, 孙看军, 等. 麦麸纤维素与腐植酸复合保水剂的制备及性能[J]. 水土保持通报, 2018,38(2):253-257. DOI: 10.13961/j.cnki.stbctb.2018.02.041.
ZHENG Yanping, LIU Fang, SUN Kanjun, et al. Synthesis and Property of Superabsorbent Compound of Cellulose Extracted from Wheat Bran with Humic Acid[J]. Bulletin of Soiland Water Conservation, 2018, 38(2): 253-257. DOI: 10.13961/j.cnki.stbctb.2018.02.041.
[目的]研究利用麦麸提取的纤维素与腐植酸共聚制备复合保水剂的方法及其性能,以解决现有保水剂生物难降解,成本高,污染大,再生性能差等问题。[方法]采用碱法从麦麸中提取纤维素,首次与腐植酸、丙烯酸水溶液聚合制备了复合保水剂。用扫描电子显微镜(SEM)、热重分析(TG)分别对树脂的表面形貌、热稳定性进行了表征,考查了NaOH、引发剂、交联剂、麦麸、腐植酸用量对复合保水剂吸水率的影响,并对温度、不同交联剂、再生性能进行了探讨。[结果]麦麸质量0.15 g,丙烯酸20 ml,交联剂(N,N-亚甲基双丙烯酰胺)的质量是丙烯酸质量的0.03%,引发剂的质量是丙烯酸质量的0.8%,腐植酸0.1 g,NaOH浓度80%,温度80℃时,吸水倍率最高,蒸馏水达到了989 g/g,对地下水的吸水倍率达到了120.34 g/g。对盐水的吸水倍率达到了62.76 g/g。[结论]实验方法制备的保水剂再生性能、热稳定性良好,较文献报道的保水剂吸水效果优异,可以在实际生产和生活中推广应用。
[Objective] The preparation method of superabsorbent compound by copolymerization of cellulose extracted from wheat bran with humic acid and its performance were studied in order to solve the existing problems of popular water retention agents
such as difficult to biodegrade
high cost
serious pollution
poor regeneration and others.[Methods] The composite superabsorbent compound was prepared for the first time using cellulose which was extracted from wheat bran by alkali method
with humic acid as an additive and acrylic acid as monomer by polymerization in this study. Its surface morphology and thermal stability were characterized respectively by scanning electron microscopy(SEM)
thermal gravity analysis(TG). The effects of dosage on sodium hydroxide
initiator
crosslinking agent
cellulose and humic acid were investigated. Moreover
the effects of temperature
different kinds of crosslinking agents and regeneration properties were also discussed.[Results] The results indicated that:when 0.15 g of cellulose and 20 ml of acrylic were inputted
the cross-linking agent (N
N-methylene double acryl amide) would be 0.03% of acrylic
the initiator will be 0.8% of acrylic. When humic acid was 0.1 g
sodium hydroxide was 80%
the reactive temperature was 80℃
the maximum absorption rates of the superabsorbent to distilled water reached 989 g/g
to underground water and brine
the values were 120.34 g/g and 62.76 g/g.[Conclusion] The superabsorbent compound showed good thermal stability and renewable performance. In comparison with the similar products reported in relative references
it has better water absorbing properties
and could be popularized and applied in real life.
马东卓,张帅,何乾坤.纤维素基高吸水材料研究进展[J].化工进展,2014,33(7):1786-1790.
李娟,沈士军,等.吸水树脂改性研究进展[J].合成树脂及塑料,2011,28(3):78-82.
马斐,程冬炳,等.聚丙烯酸类高吸水树脂的合成及吸水机理研究进展[J].武汉工程大学学报,2011,33(1):4-9.
Chu Mo, Huang Zhanbin, Xu Bang, et al. Preparation characterization and salt-resistance of a coal based super absorbent composite[J]. Mining Science and Technology, 2010,20(6):864-871.
Dutkiewicz J K. Superabsorbent materials from shellfish waste:A Review[J]. Journal of Biomedical Materials Research, 2002,63(3):373-381.
朱红,邹静,王芳辉.聚丙烯酸钾与腐植酸复合高吸水性树脂的合成研究[J].现代化工,2006,26(11):42-44.
元艳,李季,韩春艳.丙烯酸-2-丙烯酰胺基-2-甲基丙磺酸-滤渣高吸水性树脂的制备[J].化工新型材料,2009,37(4):42-44.
龚磊,连延超,等. 柚皮粉复合农林保水剂的合成及其保水性能研究[J].化工新型材料,2017,45(6):261-263.
吴杰辉.可降解性高吸水树脂的设计、合成及综合性能研究[D].湖北武汉:武汉工程大学,2015.
贾振宇,崔英德.丙烯酸系高吸水性树脂的高性能化研究[D].陕西西安:西北工业大学,2006.
史俊,王涛.腐植酸吸水性树脂的合成及性能的研究[J].西安石油大学学报:自然科学版,2008,23(4):53-61.
邹静.腐植酸保水剂的制备研究[D].北京:北京交通大学,2006.
王昱程,张玉斌,邬乃鹏,等.腐植酸-纤维素复合农林保水剂的制备及性能[J].水土保持通报,2014,34(2):134-138.
常宪辉.多酶分步法生产小麦麸膳食纤维粉的研究[D].湖北武汉:武汉工业大学,2008.
0
浏览量
986
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621