1. 河西学院, 农业与生物技术学院,甘肃,张掖,734000
2. 山丹军马场自然保护站,甘肃,张掖,734000
纸质出版:2017
移动端阅览
张慧瑛, 樊丹阳, 卢妹妹, 等. 利用小麦秸秆制备的保水剂性能研究[J]. 水土保持通报, 2017,37(2):193-198.
ZHANG Huiying, FAN Danyang, LU Meimei, et al. Synthesis and Water-holding Performance of Water Retaining Agent Made from Wheat Straw[J]. Bulletin of Soiland Water Conservation, 2017, 37(2): 193-198.
张慧瑛, 樊丹阳, 卢妹妹, 等. 利用小麦秸秆制备的保水剂性能研究[J]. 水土保持通报, 2017,37(2):193-198. DOI: 10.13961/j.cnki.stbctb.2017.02.030.
ZHANG Huiying, FAN Danyang, LU Meimei, et al. Synthesis and Water-holding Performance of Water Retaining Agent Made from Wheat Straw[J]. Bulletin of Soiland Water Conservation, 2017, 37(2): 193-198. DOI: 10.13961/j.cnki.stbctb.2017.02.030.
[目的] 以小麦秸秆纤维素接枝丙烯酸制备保水剂,并检测各因素对保水剂吸水性能的影响,探索制备保水剂的最佳反应条件,以期制备出成本低,降解性好,保水性高的新型保水剂。[方法] 采用水溶液聚合法制备保水剂,并通过单因素试验和正交试验来确定最佳反应条件,对合成产物的吸液倍率、保水性能和表观形态进行测定与表征。[结果] 温度为70 ℃,去离子水用量为160 ml,2.0%N,N'-亚甲基双丙烯酰胺(MBAM)用量为9 ml,引发剂(过硫酸钾:硫代硫酸钠=3∶1)与丙烯酸单体比为2.0%,丙烯酸中和度为70%,反应时间为1 h,合成的保水剂具有较高的吸水或盐水倍率,1 g保水剂吸0.9%NaCl溶液41.2 g/g,吸去离子水430.9 g/g。红外光谱分析和电镜扫描结果表明,保水剂胶体接枝聚合成功,胶体具有良好的表面形态。[结论] 制备的保水剂吸液速率快、重复吸水效果较好。保水剂在氯化铁溶液中吸水倍率最高,达到113 g/g。复合离子溶液中,在离子浓度为1 g/L时吸水倍率最高达57 g/g。
[Objective] In order to create an excellent water-holding material
using wheat straw as raw material
acrylic acid(AA) as graft monomers
the N
N'-methylene bisacrylamide as crosslinker and the potassium peroxydisulfate as free radical evocating agent
the super absorbent polymer was prepared by water solution polymerization. [Methods] The optimized reaction conditions were determined based on a single factor and an orthogonal experiment. In addition
the absorbency
retaining capacity and surface morphology of the obtained water retention agent in the experiment were characterized. [Results] Optimal reaction conditions were as follows: temperature 70 ℃
deionized water 160 ml
2%N
N-methylene double acrylamide solution 9 ml
initiator accounted for acrylic monomer 2%
degree of neutralization of AA was 70%
reaction time was 1 h. Under this experimental conditions
the water retention agent had stronger water absorbency
and the 1 g dry super absorbent polymer can absorb water 41.2 g/g in 0.9% NaCl solution and 430.9 g/g in distilled water. The colloid graft polymerization of water retention agent was successful
and the surface morphology was good. [Conclusion] Super absorbent polymer has faster fluid and good characteristics of water retention and reuse. The product can absorb water 113 g/g in ferric chloride solution of the different ions solution and the maximum water absorption was 57 g/g in compound ion solution.
左广玲,叶红勇,李入林,等.利用大豆秸秆制备农用保水剂及其保水性能研究[J].河南农业科学,2010(4):50-52.
Krul L P, Nareiko E I, Matusevich Y I, et al. Water super absorbents based on copolymers of acrylamide with sodium acrylate[J]. Polymer Bulletin, 2000,45(2):159-165.
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郭焱,李小燕,李存本,等.小麦秸秆制备农用高吸水性树脂[J].精细化工,2006,23(4):322-326.
Qu Changsheng, Li Bing, Wu Haisuo, et al. Controlling air pollution from straw burning in China calls for efficient recycling[J]. Environment Science Technology, 2012,46(15):7934-7936.
傅绪成,陈蒙,许庆庆,等.以大麻秸秆等废弃物为原料的农用保水剂制备研究[J].皖西学院学报,2015(5):116-120.
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吴文娟.纤维素系高吸水性树脂的研究进展[J].纤维素科学与技术,2006,14(4):57-61.
郭焕,刘国军,张桂霞,等.淀粉接枝丙烯酸高吸水树脂的性能研究[J].化工新型材料,2013,41(3):119-121.
孙琳,路乃群,王存国,等. K
2
S
2
O
8
-Na
2
S
2
O
3
引发淀粉与丙烯酸接枝产物吸水性能的主要影响因素[J].化工科技,2008,16(1):8-11.
陈日清,储富祥,金立维,等.一种耐盐保水剂的制备及其性能研究[J].南京林业大学学报:自然科学版,2006,30(2):33-37.
Lim K Y, Yoon K J, Kim B C. Highly absorbable lyocell fiber spun from celluloses/hydrolyzed starch-g-PAN solution in NMMO monohydrate[J]. European Polymer Journal, 2003,39(11):2115-2120.
白文波,张浣中,宋吉青,等.保水剂重复吸水性能的比较研究[J].中国农业科技导报,2010,12(3):92-97.
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